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- W2142000725 abstract "Alkylidyne groups coordinated to a trinuclear support without metal–metal bonds in a TiO2-like arrangement, [{TiCp*(μO)}3(μ3-CR)], allow the insertion of CO or isocyanide molecules under mild reaction conditions. In the reaction products, the Ti3O3 core of this organometallic support stabilizes unexpected bonding, as found in complexes 1 and the “zwitterionic” derivative 2. [Ti]=Ti(η5-C5Me5)." @default.
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- W2142000725 date "1998-07-10" @default.
- W2142000725 modified "2023-10-16" @default.
- W2142000725 title "Reactivity ofμ3-Alkylidyne Groups on an Organotitanium Oxide: Insertion of Isocyanides and Carbon Monoxide into the Complexes [{TiCp*(μ-O)}3(μ3-CR)] (R=H, Me)" @default.
- W2142000725 doi "https://doi.org/10.1002/(sici)1521-3765(19980710)4:7<1206::aid-chem1206>3.0.co;2-4" @default.
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