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- W2142140354 abstract "Abstract Two approaches are described to the question of orientation of principal in-plane g axes for copper complexes of low point symmetry ( C 2 , C 2 h , C s ). In different ways these attempt to rectify deficiencies in an earlier phenomenological theory due to Hitchman, Olson, and Belford ( J. Chem. Phys. 50 , 1195 (1969)), especially the neglect of spin-orbit coupling between excited states. The new phenomenological theory yields essentially the same results as previously described but requires reinterpretation of some of the parameters which were then used. An alternative approach, based on computer diagonalization of the 10 × 10 crystal-field matrix, including spin-orbit and Zeeman interactions but neglecting covalency, yields orientations of principal g values up to 40° away from the in-plane ground-state lobes. The effects described may be understood on the basis of competition between spin-orbit and low-symmetry crystal-field effects on the excited |xz〉, |yz〉 pair of excited states." @default.
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- W2142140354 date "1977-12-01" @default.
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- W2142140354 title "Effects of excited-state spin-orbit coupling and ground-state hybridization upon the behavior of the in-plane g tensor in low-symmetry d1,9 systems" @default.
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- W2142140354 doi "https://doi.org/10.1016/0022-2364(77)90285-2" @default.
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