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• W2142318993 abstract "Abstract Four different polyimides with side chains containing undecyl spacers and 4‐fluorostilbene mesogen end groups were prepared, and their structures and the controllability of the liquid‐crystal (LC) alignment with rubbing were investigated. From X‐ray scattering and differential scanning calorimetry data, pyromellitic dianhydride (PMDA)‐, benzophenone‐3,3′,4,4′‐tetracarboxylic dianhydride (BTDA)‐, and 4,4′‐oxydi(phthalic anhydride) (ODPA)‐based polyimides were shown to have layered structures and short‐range ordering. Pretilt angles of LCs on the rubbed surfaces were 1–9°, depending on the rubbing density and backbone. In particular, the long undecyl spacers caused the mesogenic stilbene end groups to lie next to the main chain, resulting in a reduction in the pretilt angles. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1800–1809, 2001" @default.
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• W2142318993 date "2001-04-04" @default.
• W2142318993 modified "2023-10-18" @default.
• W2142318993 title "Synthesis and characterization of novel polyimides bearing a side chain composed of stilbene mesogen and undecyl spacer and the alignment ability of nematic liquid-crystal molecules" @default.
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• W2142318993 doi "https://doi.org/10.1002/pola.1157" @default.
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