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• W2142337900 abstract "Abstract Copper-catalyzed γ-selective substitution of allylic carbonates with diboron provides a new method for the efficient synthesis of allylboronates. Optically active α-chiral allylboronates were synthesized through the reaction of chiral allylic carbonates with bis(pinacolato)diboron in the presence of achiral Cu(I)-catalyst with highly efficient chirality transfer. Additionally, in the presence of a chiral Cu(I) catalyst, optically active α-chiral allylboronates were obtained with >90 % ee through the reaction of prochiral substrates with the diboron." @default.
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• W2142337900 date "2008-01-01" @default.
• W2142337900 modified "2023-10-11" @default.
• W2142337900 title "Copper-catalyzed substitution of allylic carbonates with diboron: A new approach to allylboronate synthesis" @default.
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• W2142337900 doi "https://doi.org/10.1351/pac200880051039" @default.
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