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- W2142356557 abstract "During the 13th and 14th centuries, the commune of Massa Marittima successfully exploited the nearby base-metal mines (copper, lead and silver). Several smelting sites were active. Twenty-seven slag specimens were sampled at Marsiliana, Arialla and Rocchette Pannocchieschi. Slags have been analysed by X-ray fluorescence spectrometry, X-ray powder diffraction, optical microscopy, scanning electron microscopy and energy dispersive X-ray spectrometry. The slags from the three sites differ in chemical composition. The most abundant pyrometallurgic phases in the glassy matrix are calcic clinopyroxene, kirschsteinite, melilite, accompanied by spinel, wüstite, sulphides, metals and metal alloys. The three sites produced more than 2000 t of copper, 6000 t of lead and 2 t of silver. Copper was mostly smelted at Marsiliana, and silver-bearing lead was smelted at Arialla and Rocchette Pannocchieschi. The minerals underwent only a mild roasting prior to smelting. Flux lime was added to the mineral charge, and the resulting viscosity index of the melts (from 0.9 to 3.7) assured effective metal segregation. Furnace temperatures reached 1150–1300 °C." @default.
- W2142356557 created "2016-06-24" @default.
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- W2142356557 date "2002-07-01" @default.
- W2142356557 modified "2023-09-24" @default.
- W2142356557 title "Chemical and textural characterisation of medieval slags from the Massa Marittima smelting sites (Tuscany, Italy)" @default.
- W2142356557 cites W1981001956 @default.
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- W2142356557 doi "https://doi.org/10.1016/s1296-2074(02)01176-7" @default.
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