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- W2142494405 abstract "The process of formation and decomposition of solid films of germanium monoxide from GeO vapor was studied using physical and chemical approaches. A model clarifying the metastability of solid GeO is developed. According the model, the structure of atomic orbitals (σ- and n- bonds) of a GeO molecule causes the stability of GeO in gaseous phase. After condensation GeO(gas) GeO(solid), the atomic orbitals of Ge are transformed in lowest energy sp3-hybridized configuration, this configuration is universal both for Ge and for Ge0 2 . The decomposition of GeO(solid) into Ge and GeO 2 is caused by relaxation of deformation energy appearing due to big difference of Ge-Ge and Ge-O bond length." @default.
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- W2142494405 date "2009-10-01" @default.
- W2142494405 modified "2023-09-25" @default.
- W2142494405 title "The decomposition mechanism of metastable solid GeO film" @default.
- W2142494405 cites W1984658586 @default.
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- W2142494405 doi "https://doi.org/10.1109/internano.2009.5335633" @default.
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