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• W2142510174 abstract "A versatile glycosylation reaction is used to establish the process of sulfoxide covalent catalysis. Hemiacetals are activated by benzenesulfonic anhydride and a dialkyl sulfoxide catalyst, nBu2SO, for coupling with various nucleophiles (Nu; see scheme, TTBP=2,4,6-tri-tert-butylpyridine). The sulfoxide catalyst functions uniquely in three capacities, first as an O nucleophile, then as a S+ electrophile, and finally as a leaving group to fulfill turnover. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2003/z52761_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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• W2142510174 date "2003-12-08" @default.
• W2142510174 modified "2023-10-16" @default.
• W2142510174 title "Sulfoxide Covalent Catalysis: Application to Glycosidic Bond Formation" @default.
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• W2142510174 doi "https://doi.org/10.1002/anie.200352761" @default.
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