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• W2142516950 abstract "A simple procedure has been developed to select ions in a Fourier transform ion cyclotron resonance (FT-ICR) ion trap. This procedure involves the use of correlated single- and swept-frequency excitation fields to eject unwanted ions from the FT-ICR ion trap. Correlation with the effective cyclotron frequency of the ions which are to be selected leads to optimization of the parameters controlling the single- and swept-frequency excitation fields, as a result of which accumulation of off-resonance excitation energy is prevented during the ion ejection event. Accordingly, it is demonstrated that the correlated harmonic excitation field (CHEF) procedure, which readily can be implemented in the data acquisition system of FT-ICR instruments, can conveniently be used for the selection of thermally labile ions. Hence, the CHEF procedure can be a generally applicable experimental tool for MS-MS studies, especially for studies requiring thermal ions such as ion/molecule reaction kinetic studies, and determinations of absolute threshold energies of ion decomposition reactions. The CHEF procedure can minimize the duration of the ion selection event, which especially is beneficial for ion selections which require high mass resolution. It is experimentally shown that ion selections which require a mass resolution beyond 60 000 do not suffer from ion loss." @default.
• W2142516950 created "2016-06-24" @default.
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• W2142516950 date "1997-11-01" @default.
• W2142516950 modified "2023-10-10" @default.
• W2142516950 title "Mass selection of ions in a Fourier transform ion cyclotron resonance trap using correlated harmonic excitation fields (CHEF)" @default.
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• W2142516950 doi "https://doi.org/10.1016/s0168-1176(97)00186-9" @default.
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