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- W2142590087 abstract "The syntheses of platinum(II) complexes of bis(dimethylphosphinylmethylene)amine and bis(aminomethyl)phosphinic acid were investigated. In the case of bis(dimethyl-phosphinylmethylene)amine the reaction with K2[PtCl4] yields the potassium amino-trichloroplatinate K[PtCl3L] (L = bis(dimethylphosphinylmethylene)amine), which was characterized by multinuclear (1H, 13C, 31P, and 195Pt) NMR spectroscopy in solution. Bis(aminomethyl)phosphinic acid reacts with K2[PtCl4] under strictly controlled pH conditions to give colorless crystals of the cisplatin analog K[PtCl2L′] (L′ = bis(aminomethyl)phosphinate). This complex was characterized by multinuclear NMR spectroscopy in solution as well as by single-crystal X-ray diffraction in the solid state. The bis(aminomethyl)phosphinate coordinates to platinum via both amino functions, thus acting as a chelating ligand." @default.
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- W2142590087 date "2012-03-07" @default.
- W2142590087 modified "2023-09-23" @default.
- W2142590087 title "Synthesis and characterization of new platinum(II) phosphinate complexes" @default.
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- W2142590087 doi "https://doi.org/10.1080/00958972.2012.666797" @default.
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