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- W2142660351 abstract "The crystallization kinetics of isotactic polypropylene (iPP) and nucleated iPP with two organic phosphates, sodium salt (NA7) and triglyceride ester (NA8) of 2,2'-methylene-bis(4,6-di-tert-butylphenyl) phosphoric acid, were investigated by means of a differential scanning calorimeter under isothermal and nonisothermal conditions. During isothermal crystallization, a modified Avrami equation was used to describe the crystallization kinetics. Moreover, kinetics parameters, such as the Avrami exponent, n, the crystallization rate constant, k, and the half-time of crystallization, τ1/2, are compared. The results showed that a dramatic decrease of the half-time of crystallization, as well as a significant increase of the overall crystallization rate, were observed in the presence of the organic phosphates. During nonisothermal crystallization, the primary crystallization was analyzed using the Ozawa model, leading to similar Avrami exponents for iPP and iPP/NA7, which means simultaneous nucleation with three-..." @default.
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- W2142660351 date "2003-01-08" @default.
- W2142660351 modified "2023-09-25" @default.
- W2142660351 title "Crystallization Kinetics of Nucleated Polypropylene with Organic Phosphates" @default.
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- W2142660351 doi "https://doi.org/10.1081/mb-120021597" @default.
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