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- W2142828354 abstract "A new convenient method has been developed for the synthesis of beta-hydroxy thioethers with aryl disulfides and zinc powder in the presence of catalytic amounts of Bi(OTf)3 and Bi(TFA)3 in acetonitrile. The present method is very simple and the conditions tolerate a variety of acid-sensitive protecting groups. On the other hand, alkyl or benzyl disulfides afforded no corresponding thioethers under similar conditions. Then the observed regio- and chemoselectivity can be considered as a noteworthy advantage of this method." @default.
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- W2142828354 date "2005-06-01" @default.
- W2142828354 modified "2023-10-18" @default.
- W2142828354 title "Bi(OTf)3 or Bi(TFA)3 catalyzed efficient, regio- and chemoselectively synthesis of beta-hydroxy thioethers from aryl disulfides in the presence of zinc powder" @default.
- W2142828354 cites W583419886 @default.
- W2142828354 doi "https://doi.org/10.1590/s0103-50532005000400032" @default.
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