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- W2142858082 abstract "We study a nonmonotonic behavior with temperature of the activation volume <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi>Δ</mml:mi><mml:msub><mml:mtext>V</mml:mtext><mml:mi>β</mml:mi></mml:msub></mml:mrow></mml:math> of secondary relaxation in PPGE [Poly[(phenyl glycidyl ether)-co-formaldehyde]] and PVAc [Poly(vinyl acetate)] glass formers. Our results show that the non-monotonic behaviour of secondary relaxation does not depend on the type of the secondary relaxation. Moreover, the study of secondary relaxation under pressure at isothermal paths shows two different behaviours of <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi>Δ</mml:mi><mml:msub><mml:mtext>V</mml:mtext><mml:mi>β</mml:mi></mml:msub></mml:mrow></mml:math> in the glassy state (which describe two different types of glasses); for temperatures higher than the glass transition temperature (Tg), <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi>Δ</mml:mi><mml:msub><mml:mtext>V</mml:mtext><mml:mi>β</mml:mi></mml:msub></mml:mrow></mml:math> increases with a decrease of the temperature while at temperatures lower than Tg, <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi>Δ</mml:mi><mml:msub><mml:mtext>V</mml:mtext><mml:mi>β</mml:mi></mml:msub></mml:mrow></mml:math> decreases with a decrease of the temperature." @default.
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- W2142858082 date "2011-07-25" @default.
- W2142858082 modified "2023-09-24" @default.
- W2142858082 title "Temperature Dependence of the Activation Volume of Secondary Relaxation in Glass Formers" @default.
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- W2142858082 doi "https://doi.org/10.5402/2011/460751" @default.
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