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- W2142921925 abstract "Abstract An examination of the literature reveals that only a limited number of monosubstituted cycloheptadiene compounds have been reported. An obvious synthetic route to 5-substituted -1, 3-cycloheptadiene derivatives would be the reaction of nucleophiles with the cycloheptadienyl cation, but this pathway is generally unsuccessful due to the limited stability of the cation. On the other hand, the iron tricarbonyl complex of this cation shows remarkable stability1 and an ability to react with nucleophiles2. If the -Fe(CO)3 group could be removed easily, a facile route to this family of organic compounds would be available. This work reports our investigation of the range of nucleophiles that can be utilized and the oxidizing agents that can remove efficiently the -Fe(CO)3 group." @default.
- W2142921925 created "2016-06-24" @default.
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- W2142921925 date "1979-04-10" @default.
- W2142921925 modified "2023-09-27" @default.
- W2142921925 title "ChemInform Abstract: GENERAL SYNTHETIC ROUTE TO MONOSUBSTITUTED CYCLOHEPTADIENES FROM ORGANOMETALLIC COMPOUNDS" @default.
- W2142921925 cites W4236665493 @default.
- W2142921925 doi "https://doi.org/10.1002/chin.197915193" @default.
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