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- W2142937975 abstract "Abstract Acyclic multidentate ligands consisting of an oligooxyethylene chain (di-, tri-, tetra-, and penta-) and two terminal rigid quinaldate end groups were newly prepared and their complexation properties with alkali metal cations were estimated by the solvent extraction method to indicate a better affinity for K+. Among them, the tetraethylene glycol derivative showed the highest K+ binding on about the same level as 18-crown-6. Their conformations in solution and in the solid state were examined by using 1H- and 13C-NMR spectroscopy and X-ray crystal analyses, respectively. The better binding of K+ in comparison with the corresponding glymes or analogues having the same donor sites was reasonably explained by considering the effective co-ordination of the carbonyl oxygen of the ester groups and the parallel π-stacking interaction between two quinaldate surfaces." @default.
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- W2142937975 date "1993-07-01" @default.
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- W2142937975 title "Complexation of acyclic ligands having two terminal quinoline units with alkali metal cations" @default.
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- W2142937975 doi "https://doi.org/10.1080/10610279308038309" @default.
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