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- W2142976403 abstract "Using a flexible methylenebis(3,5-dimethylpyrazole) ligand (H2MDP) with different aromatic carboxylate ligands, six new complexes {[Cd(H2MDP)(OPh)](H2O)}n (1), {[Cd(H2MDP)(MPh)](H2O)1/10}n (2), {[Cd(H2MDP)(PPh)](H2O)3/2}n (3), {[Co(H2MDP)(OPh)](H2O)2}n (4), {Co(H2MDP)(MPh)}n (5), {Co(H2MDP)(HBTC)}n (6) (H2OPh = phthalic acid, H2MPh = isophthalic acid, H2PPh = terephthalic acid, H3BTC = benzene-1,3,5-tricarboxylic acid) have been isolated under hydrothermal conditions. The crystal structure analyses reveal that complexes 1 and 4 feature two-dimensional undulated sheets with 44·62 topology. Both complexes 2 and 3 contain M2L2-type metallocyclic motifs composed of two H2MDP ligands and two metal atoms, while complex 2 features a two-dimensional 44·62 network constructed from binuclear cadmium units as four connected nodes, and complex 3 shows a two-dimensional network with 63-hcb topology. Complex 5 affords a one-dimensional chain structure, and complex 6 shows a two-dimensional (4,4) network further connected into a 3D supramolecular structure connected by intermolecular hydrogen bonds and by π–π interactions. In addition, the luminescent properties of complexes 2 and 3 as well as the magnetic properties of 4 and 5 were studied." @default.
- W2142976403 created "2016-06-24" @default.
- W2142976403 creator A5008031459 @default.
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- W2142976403 date "2013-01-01" @default.
- W2142976403 modified "2023-10-17" @default.
- W2142976403 title "Auxiliary ligand-directed synthesis of a series of Cd(ii)/Co(ii) coordination polymers with methylenebis(3,5-dimethylpyrazole): syntheses, crystal structures, and properties" @default.
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- W2142976403 doi "https://doi.org/10.1039/c3dt51574e" @default.
- W2142976403 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23999828" @default.
- W2142976403 hasPublicationYear "2013" @default.
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