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- W2142988903 abstract "Shields up! Post-synthetic modification of the secondary building units in the metal–organic framework UiO-66 (Zr6O4(OH)4(O2CR)12) by dehydration and subsequent grafting of LiOtBu (see picture, green) yields a solid Li+ electrolyte with a conductivity of 1.8×10−5 S cm−1 at 293 K. As the grafting leads to screening of the anionic charge, the activation energy for ionic conduction is significantly lower than when Li+ is introduced through deprotonation. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
- W2142988903 created "2016-06-24" @default.
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- W2142988903 date "2013-03-12" @default.
- W2142988903 modified "2023-10-16" @default.
- W2142988903 title "Ionic Conductivity in the Metal-Organic Framework UiO-66 by Dehydration and Insertion of Lithium<i>tert</i>-Butoxide" @default.
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- W2142988903 doi "https://doi.org/10.1002/chem.201300326" @default.
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