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• W2142993667 abstract "Abstract A kinetic study of the living cationic polymerization of p ‐methoxystyrene using 1‐(4‐methoxyphenyl)ethanol ( 1 )/B(C 6 F 5 ) 3 initiating system in a mixture of CH 3 CN with CH 2 Cl 2 1:1 (v/v) at room temperature was carried out utilizing a wide variety of conditions. The polymerization proceeded in a living fashion even in the presence of a large amount of water ([H 2 O]/[B(C 6 F 5 ) 3 ] ratio up to 20) to afford polymers whose M n increased in direct proportion to monomer conversion with fairly narrow MWDs ( M w / M n ≤ 1.3). The investigation revealed that the rate of polymerization was first‐order in B(C 6 F 5 ) 3 concentration, while a negative order in H 2 O concentration close to −2 was obtained. It was also found that the rate of polymerization decreased with lowering temperature, which could be attributed to a decreased concentration in free Lewis acid, the true coinitiator of polymerization. A mechanistic scheme to explain the kinetic behavior of living p ‐methoxystyrene polymerization is proposed, which has been validated by PREDICI simulation on multiple‐data curves obtained by 1 H NMR in situ polymerization experiment. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6928–6939, 2008" @default.
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• W2142993667 date "2008-09-16" @default.
• W2142993667 modified "2023-10-18" @default.
• W2142993667 title "Kinetic study on the living/controlled cationic polymerization of <i>p</i> -methoxystyrene coinitiated by tris(pentafluorophenyl)borane" @default.
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• W2142993667 doi "https://doi.org/10.1002/pola.23002" @default.
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