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- W2143031796 abstract "By using a d-fructose-derived chiral ketone or a d-mannitol-derived chiral amine as catalyst, the organocatalytic asymmetric epoxidation of cis-1-propenylphosphoric acid with 30% aqueous hydrogen peroxide in H2O–CH3CN mixture (∼80:20) afforded (1R, 2S)-(−)-(1,2)-epoxypropyl phosphoric acid (fosfomycin). Asymmetric epoxidation was carried out at 0 °C for 72 h to achieve 100% conversion with a maximum enantiomeric excess (e.e.) of 74%." @default.
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- W2143031796 date "2008-04-01" @default.
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- W2143031796 title "Chiral ketone- or chiral amine-catalyzed asymmetric epoxidation of cis-1-propenylphosphonic acid using hydrogen peroxide as oxidant" @default.
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- W2143031796 doi "https://doi.org/10.1016/j.molcata.2008.01.011" @default.
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