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• W2143048332 startingPage "14087" @default.
• W2143048332 abstract "A new motif for infinite metal atom wires with tunable compositions and properties is developed based on the connection between metal paddlewheel and square planar complex moieties. Two infinite Pd chain compounds, [Pd4(CO)4(OAc)4Pd(acac)2] 1 and [Pd4(CO)4(TFA)4Pd(acac)2] 2, and an infinite PdPt heterometallic chain compound, [Pd4(CO)4(OAc)4Pt(acac)2] 3, are identified by single-crystal X-ray diffraction analysis. In these new structures, the paddlewheel moiety is a Pd four-membered ring coordinated by bridging carboxylic ligands and μ2 carbonyl ligands. The planar moiety is either Pd(acac)2 or Pt(acac)2 (acac=acetylacetonate). These moieties are connected by metallophilic interactions. The results showed that these one-dimensional metal wire compounds have photoluminescent properties that are tunable by changing ligands and metal ions. 3 can also serve as a single source precursor for making Pd4Pt bimetallic nanostructures with precise control of metal composition." @default.
• W2143048332 created "2016-06-24" @default.
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• W2143048332 date "2014-10-15" @default.
• W2143048332 modified "2023-09-26" @default.
• W2143048332 title "A Motif for Infinite Metal Atom Wires" @default.
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• W2143048332 doi "https://doi.org/10.1002/anie.201408461" @default.
• W2143048332 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25319757" @default.
• W2143048332 hasPublicationYear "2014" @default.
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