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- W2143100156 abstract "Self-assembly of octahedral Fe(II) ions and linear perylene bisimide (PBI) dyes with 2,2'-bipyridine groups covalently attached at the imide positions quantitatively yields an Fe4(PBI)6 tetrahedron by the directional bonding approach. With an edge length of 3.9 nm and estimated internal volume >950 Å(3), tetrahedron T is one of the largest M4L6 tetrahedra ever reported. Importantly, many of the desirable photo- and electroactive properties of the PBI ligands are transferred to the nanoscale metallosupramolecule. Tetrahedron T absorbs strongly across the visible spectrum out to 650 nm and exhibits a total of 7 highly reversible electrochemical oxidation and reduction waves spanning a 3.0 V range. This facile cycling of 34 electrons between +18 and -16 charged species is likely enabled due to the porous nature of the tetrahedron that allows the necessary counterions to freely flow in and out of the host. Host-guest encapsulation of C60 by T in acetonitrile was studied by (13)C NMR spectroscopy, UV-vis spectroscopy, and ESI-MS, confirming that the tetrahedron is a suitable host for large, functional guest molecules." @default.
- W2143100156 created "2016-06-24" @default.
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- W2143100156 creator A5080213784 @default.
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- W2143100156 date "2013-10-08" @default.
- W2143100156 modified "2023-09-23" @default.
- W2143100156 title "Giant Electroactive M<sub>4</sub>L<sub>6</sub> Tetrahedral Host Self-Assembled with Fe(II) Vertices and Perylene Bisimide Dye Edges" @default.
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- W2143100156 doi "https://doi.org/10.1021/ja4083039" @default.
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