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- W2143113732 abstract "The development of the dynamic glass transition in styrene-butadiene copolymers has been investigated by dielectric spectroscopy in the frequency range from 10-2 to 106 Hz. Two processes were detected and attributed to the α- and β-relaxations. The α relaxation time has a non-Arrhenius temperature behavior that is highly dependent on styrene content while the β relaxation time shows an Arrhenius behavior with an activation energy that is independent of styrene-content. Furthermore, the shape of the α-relaxation is strongly influenced by the styrene content while the shape of β-relaxation is not. We interpret these results as follows. The observed β-relaxation is primarily due to local motions of butadiene monomers and therefore not affected by the presence of styrene. The α-relaxation, on the other hand, is highly sensitive to the styrene content due to its cooperative character." @default.
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- W2143113732 date "2002-04-20" @default.
- W2143113732 modified "2023-10-17" @default.
- W2143113732 title "Dielectric α- and β-Relaxations in Uncured Styrene Butadiene Rubber" @default.
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- W2143113732 doi "https://doi.org/10.1021/ma010990o" @default.
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