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- W2143138488 abstract "Transannular hydrogen bonding stabilizes a left-handed double helical conformation in the tryptophan-derived tetraazacyclooctadecane 1 both in solution and the solid state, whereas the analogous tryptamine-derived macrocycle 2 shows less tendency towards intramolecular hydrogen bonding and does not exist as a helix in the crystal. Azamacrocycles 1 and 2 are synthesized by a novel method and their secondary structure analysed by NMR spectroscopy, circular dichroism and X-ray diffraction. Molecular modelling does not account for the conformational differences between 1 and 2." @default.
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- W2143138488 date "1996-01-01" @default.
- W2143138488 modified "2023-10-17" @default.
- W2143138488 title "Indole-fused tetraazacyclooctadecanes: double-helical macrocycles" @default.
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- W2143138488 doi "https://doi.org/10.1039/p19960002427" @default.
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