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- W2143141983 abstract "A series of monofunctionalized hydroquinol oligoether chains terminated by thiols were designed and synthesized from unsymmetric starting materials in good yields by multi-procedure reactions at mild temperatures. In a thermodynamically controlled self-assembly process, several pseudorotaxanes based on the π-electron-rich hydroquinol oligoether thiols and π-electron deficient cyclobis(paraquat-p-phenylene) (CPQT) were formed. Furthermore, a gold cation was added to the self-assembly systems and 1H NMR studies on the thiol/Au systems revealed that Au3+ is an efficient terminal stopper of pseudorotaxanes or rotaxanes; the pseudorotaxane can be unthreaded or rethreaded at different temperatures. These could be a basis for the future development of mechanoelectrical and photoelectrical communication systems, and devices capable of storing and processing information." @default.
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- W2143141983 date "2003-06-01" @default.
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- W2143141983 title "Synthesis ofo-?-mercapto [poly(ethyleneoxy)]-o'-alkylhydroquinol derivatives and formation of novel pseudorotaxanes" @default.
- W2143141983 doi "https://doi.org/10.1080/0278611031000138027" @default.
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