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• W2143144928 startingPage "3538" @default.
• W2143144928 abstract "The aggregate structures of two di-n-alkyl-phosphate anions (di-n-alkyl: n-butyl(n-dodecyl)(BDoP) and n-hexyl(n-dodecyl)(HDoP)) in water were studied by the use of SANS, cryo-TEM, Raman scattering, 13C NMR, and selective NOE (1H{1H}) techniques. The results of SANS indicated that the different −CH2– lengths of the short chain led to a marked difference in the aggregational behavior of BDoP and HDoP. Cryo-TEM added direct images to support the average aggregation size and shape predicted by the SANS analyses. Raman scattering, 13C NMR, and selective NOE results provided further evidence that variation of molecular conformations strongly contributed to variation in the shape of the aggregates. In particular, selective NOE was a powerful technique for investigating the dynamic structures of the hydrocarbon chains during growth of the micelles." @default.
• W2143144928 created "2016-06-24" @default.
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• W2143144928 date "2012-03-14" @default.
• W2143144928 modified "2023-10-16" @default.
• W2143144928 title "Aggregate Structures of Asymmetric Di-Alkyl Phosphate Anions and the Role of Conformations about the Polar Region: SANS, Cryo-TEM, Raman Scattering, ¹³C NMR, and Selective NOE Studies" @default.
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• W2143144928 doi "https://doi.org/10.1021/jp300019n" @default.
• W2143144928 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22339781" @default.
• W2143144928 hasPublicationYear "2012" @default.
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