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- W2143194805 abstract "The vapor pressures of the isotopic acetylenes: C2H2, C2HD, and C2D2, have been investigated by mercury manometry. Samples of relatively pure C2HD were prepared for this purpose by low-temperature gas chromatography. The vapor pressure measurements were made from 0.5 to 800 mm pressure (125–190°K) with a precision of ∼0.01 mm. The vapor pressure isotope effects were normal with the isotope effect for C2HD being slightly larger than the rule of the mean value. The data for C2D2 showed a sharp change in the temperature dependence at 147.4°K which has been interpreted as a result of a solid–solid phase transition in C2D2. The experimental results have been considered in the light of the statistical theory of isotope effects in condensed systems. A model calculation made within the framework of this theory is in agreement with the experimental data." @default.
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- W2143194805 date "1970-01-15" @default.
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- W2143194805 title "Vapor Pressure Isotope Effects of the Deuterated Acetylenes" @default.
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- W2143194805 doi "https://doi.org/10.1063/1.1673013" @default.
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