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- W2143200377 abstract "Abstract A facile and expedient iodocyclization of 4‐(2‐prop‐1‐ynylphenyl)‐1 H ‐pyrroles towards the synthesis of polysubstituted 3 H ‐benzo[ e ]indoles is reported. The transformation was optimized and the best results were obtained by using iodine (1.2 equiv,) in dichloromethane, and potassium carbonate as base. The starting 1,2,3,4‐tetrasubstituted pyrroles were efficiently obtained by means of a nickel(II) chloride‐promoted four‐component (nitromethane, amine, 2‐alkynylbenzaldehyde and ethyl acetoacetate) reaction. Further functionalization of the resulting 5‐iodoheterocycles was also explored. magnified image" @default.
- W2143200377 created "2016-06-24" @default.
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- W2143200377 creator A5088105899 @default.
- W2143200377 date "2015-09-28" @default.
- W2143200377 modified "2023-10-06" @default.
- W2143200377 title "Expedient Iodocyclization Approach Toward Polysubstituted 3<i>H</i>‐Benzo[<i>e</i>]indoles" @default.
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- W2143200377 doi "https://doi.org/10.1002/adsc.201500275" @default.
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