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- W2143242005 abstract "Monosubstituierte Cyclooctatetraene des Typs C8H7PR2 mit R = C2H5, t-C4H9 und C6H5 wurden erstmals dargestellt und chemisch sowie spektroskopisch charakterisiert. Die Temperaturabhängigkeit der NMR-Spektren der thermisch genügend stabilen tert-Butylverbindungen C8H7P(t-C4H9)2 und [C8H7P(t-C4H9)2CH3] I liefern Einblicke in die Dynamik der Doppelbindungsverschiebung, der Ringinversion und der Rotation um die (Ring-)C P-Bindung. Dialkyl- and Diarylphosphinocyclooctatetraenes: A New Class of Compounds of Relevance for Conformational Analysis and Coordination Chemistry Monosubstituted cyclooctatetraenes of the type C8H7PR2 (with R = C2H5, t-C4H9. and C6H5) have been prepared for the first time and characterized both by their chemical properties and spectra. The temperature dependence of the NMR spectra of the tert-butyl compounds C8H7P- (t-C4H9)2 and [C8H7P(t-C4H9)2CH3] I, which exhibit satisfactory thermal stabilities, leads to detailed insights into the dynamics of the migration of the double bonds, of the ring inversion, and of the rotation around the (ring-)CP bond." @default.
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- W2143242005 date "1979-01-01" @default.
- W2143242005 modified "2023-10-14" @default.
- W2143242005 title "Dialkyl‐ und Diarylphosphinocyclooctatetraene: Eine neue Klasse von konformationsanalytisch und koordinationschemisch interessanten Verbindungen" @default.
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- W2143242005 doi "https://doi.org/10.1002/cber.19791120112" @default.
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