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• W2143281687 abstract "Reaction of copper(II) complex 1X supported by the tridentate bis(pyridylmethyl)amine ligand containing m-substituted phenyl groups at the 6-positions of the pyridine rings (LX) with H2O2 in the presence of triethylamine (NEt3) in acetone generates a copper(II)−alkylperoxo species 2X [2-hydroxy-2-hydroperoxypropane (HHPP) adduct]. The alkylperoxo intermediate 2X undergoes an efficient aromatic ligand hydroxylation reaction, producing a phenolate complex 4X via another intermediate 3X. Kinetic studies on the aromatic hydroxylation process are reported together with spectral characterization of 2X." @default.
• W2143281687 created "2016-06-24" @default.
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• W2143281687 date "2007-05-16" @default.
• W2143281687 modified "2023-10-12" @default.
• W2143281687 title "Aromatic Hydroxylation Reactivity of a Mononuclear Cu(II)−Alkylperoxo Complex" @default.
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• W2143281687 doi "https://doi.org/10.1021/ja071623g" @default.
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