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- W2143405671 abstract "Abstract Aluminophosphate glasses with compositions 50Li 2 O– x Al 2 O 3 –(50 − x )P 2 O 5 have been synthesized and analyzed in the x = 0–10 range. The influence of alumina content on the glass transition temperature ( T g ), crystallization temperature, thermal stability, density and ionic conductivity has been investigated. When Al 2 O 3 substitutes for P 2 O 5 , T g increases in all glass compositions. Crystallization stability has been found to be a function of alumina content. Ionic conductivity has been studied by impedance spectroscopy. Ionic conductivity and density exhibit a non-linear and non-additive change with a maximum at 6.25 mol% of Al 2 O 3 . IR spectroscopy study has indicated the phosphate network depolymerization. NMR technique revealed dramatic structural changes in the glass at x > 6.25. These changes lead to extreme behavior of molar volume and, as a consequence, to a maximum in ionic conductivity." @default.
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- W2143405671 date "2015-12-01" @default.
- W2143405671 modified "2023-09-25" @default.
- W2143405671 title "Extreme behavior of Li-ion conductivity in the Li2O–Al2O3–P2O5 glass system" @default.
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- W2143405671 doi "https://doi.org/10.1016/j.jnoncrysol.2015.10.003" @default.
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