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- W2143528266 abstract "The phenol catalysed Johnson orthoester-Claisen rearrangement of allylic alcohol (1R)-6, proceeds via two possible ketene-acetal transition states TS-1 and TS-2, to afford a 1:10 mixture of diastereomers. The transition state configuration of the C-1 methyl group (axial or equatorial) is proposed to be the dominating factor dictating whether the sigmatropic rearrangement takes place from the convex or concave face of the starting material." @default.
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- W2143528266 date "2009-03-27" @default.
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- W2143528266 title "Synthetic studies towards the anti-inflammatory agent, oleocanthal using a Johnson–Claisen (orthoester) rearrangement strategy" @default.
- W2143528266 cites W1522110495 @default.
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- W2143528266 doi "https://doi.org/10.3998/ark.5550190.0010.706" @default.
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