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• W2143631859 endingPage "11082" @default.
• W2143631859 startingPage "11078" @default.
• W2143631859 abstract "The cage compound [DippP5 Cl][GaCl4 ] (Dipp=2,6-diisopropylphenyl) reacts with an NHC (N-heterocyclic carbene) by an unprecedented [3+2] fragmentation of the P5 (+) core. This yields an imidazoliumyl-substituted P3 species featuring a triphosphaallyl anion motif and a neutral P2 compound. The mechanism of the fragmentation reaction was elucidated by means of experimental and quantum chemical methods." @default.
• W2143631859 created "2016-06-24" @default.
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• W2143631859 date "2013-08-22" @default.
• W2143631859 modified "2023-10-13" @default.
• W2143631859 title "[3+2] Fragmentation of an [RP₅Cl]⁺Cage Cation Induced by an N-Heterocyclic Carbene" @default.
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• W2143631859 doi "https://doi.org/10.1002/anie.201302914" @default.
• W2143631859 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24038818" @default.
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