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- W2143651567 abstract "The bromination of fluoro-, chloro-, and bromo-cyclohexane and chloro- and bromo-cyclopentane has been investigated in the gas phase using a flow system. Unlike previous work in solution and in a static gas phase apparatus, normal directive effects were observed, and no olefinic products were obtained. These results suggest that the high yields of 1,2-dibromoalkanes reported previously in solution phase experiments are not due to ‘anchimeric assistance’ although ‘bridging’ by the substituent may be an important factor." @default.
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- W2143651567 date "1973-01-01" @default.
- W2143651567 modified "2023-09-23" @default.
- W2143651567 title "Free-radical substitution in aliphatic compounds. Part XXVIII. The gas-phase bromination of halogenocyclohexanes and halogenocyclopentanes in a fast flow reactor" @default.
- W2143651567 doi "https://doi.org/10.1039/p29730001346" @default.
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