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• W2143673345 abstract "Synthetic approaches to 6,6′-disubstituted-2,2′-bipyridine ligands bearing carboxylic acid substituents at the 4,4′ or 5,5′-positions are described. Copper(I) complexes with these ligands have been prepared for use in copper-based dye-sensitized solar cells. The single-crystal structures of 6,6′-dimethyl-2,2′-bipyridine-4,4′-dicarboxylic acid (H24), [H36][CF3CO2]·2CF3CO2H (H26 = 6,6′-diphenyl-2,2′-bipyridine-4,4′-dicarboxylic acid) and 4[Cu(H22)(H2)]·3H2O (H22 = 6,6′-dimethyl-2,2′-bipyridine-5,5′-dicarboxylic acid) are described, as well as those of the intermediates (1E,5E)-1,6-di(2-furyl)hexa-1,5-diene-3,4-dione and 4,4′-di(2-furyl)-6,6′-dimethyl-2,2′-bipyridine (3), and the copper(I) complex [Cu(3)2][PF6]. The roles that classical and non-classical hydrogen bonding and π-stacking interactions play in determining the solid-state packing in these structures are discussed. Preliminary studies of DSCs with these complexes are reported." @default.
• W2143673345 created "2016-06-24" @default.
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• W2143673345 date "2009-01-01" @default.
• W2143673345 modified "2023-10-09" @default.
• W2143673345 title "Copper(i) complexes of 6,6′-disubstituted 2,2′-bipyridine dicarboxylic acids: new complexes for incorporation into copper-based dye sensitized solar cells (DSCs)" @default.
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• W2143673345 doi "https://doi.org/10.1039/b901346f" @default.
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