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• W2143727551 abstract "The diffusive flux of atoms required in Nabarro-Herring creep can, under certain conditions, become limited by diffusion across the space charge layer that is associated with interfaces in ionic or partly ionic materials. We derive a new equation for volume diffusional creep in such materials. Physically speaking, the creep rate is enhanced when the defect, which controls the self-diffusivity, is accumulated, and retarded when this defect is depleted, in the space charge region. For the enhanced case the factor by which the strain rate is increased quickly reaches a limit given by 1 +4LD/d, where LD is the Debye length, and d is the grain size. In the other case the retardation factor continues to increase exponentially with the space charge potential: furthermore, the retardation is most severe when the valency of the accumulating defect, which constitutes the space charge region, is small, while the valency of the depleted defect, which controls diffusion, is large. In retardation the grain size dependence of the creep rate changes from d-2 to d-1." @default.
• W2143727551 created "2016-06-24" @default.
• W2143727551 creator A5011553890 @default.
• W2143727551 creator A5053190469 @default.
• W2143727551 date "1996-01-01" @default.
• W2143727551 modified "2023-09-24" @default.
• W2143727551 title "Space-Charge-Controlled Diffusional Creep: Volume Diffusion Case+" @default.
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• W2143727551 doi "https://doi.org/10.1111/j.1151-2916.1996.tb07898.x" @default.
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