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- W214399119 abstract "Während die einfachen Merocyanin-Farbstoffe in unpolaren Lösungsmitteln eine polyenähnliche Elektronenstruktur aufweisen, gleicht sich diese in polaren Lösungsmitteln dem Polymethinzustand an. An Hand von quantenchemischen Rechenergebnissen, die für beide Grenzfälle vorliegen, sowie UV- und NMR- spektroskopischen Untersuchungen des Lösungsmitteleinflusses wird eine quantitative Beschreibung der lösungsmittelinduzierten Elektronenverschiebung vorgenommen. In non-polar solvents simple merocyanine dyes exhibit a polyene-like electron structure, while in polar solvents this corresponds to the polymethine state. On the basis of quantum chemical calculations, which are available for both limiting cases, and uv and nmr spectroscopic investigations of the solvent effect, a quantitative characterization is made of the electron shift induced by the solvent." @default.
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- W214399119 date "1970-05-01" @default.
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- W214399119 title "4. Mitteilung über solvatochromieprobleme113. Mitteilung siehe Ref. 1." @default.
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- W214399119 doi "https://doi.org/10.1016/0022-2860(70)80045-x" @default.
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