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- W2144060897 abstract "Abstract The reaction between metal salts and K2TeO2·xH2O in aqueous ethanol yielded basic metal pyrotellurito complexes, nMTe2O5·mM(OH)2·xH2O (M = Ni(II), Co(II), Cu(II), Zn(lI), Cd(II) and UO2(VI); n, m and x are whole numbers) and M2(Te2O5)3·mM(OH)3·xH2O (M = Cr(III) and Fe(III)). As the reaction medium was slightly alkaline basic pyrotellurites are formed instead of normal tellurites. The complexes are micro-crystalline, stable compounds and insoluble in all common solvents indicating their polymeric nature. IT-IR spectra of the complexes showed that the metal atoms are bridged through the terminal oxygen atoms of the pyrotellurito anions, Te2O5 2−, and the hydroxo groups of the accompanying metal hydroxides. The characteristic bending band of the hydroxo group appeared in all complexes. The electronic absorption spectra and magnetic moments of the d-elements showed that the compounds are high-spin and hexacoordinated." @default.
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- W2144060897 date "1996-12-01" @default.
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- W2144060897 title "TELLURITO COMPLEXES: BASIC METAL PYROTELLURITO COMPLEXES" @default.
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- W2144060897 doi "https://doi.org/10.1080/10426509608043481" @default.
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