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- W2144127521 abstract "α-Oxo gold carbenes generated via intermolecular oxidation of terminal alkynes are shown to be highly electrophilic and can effectively abstract halogen from halogenated solvents such as 1,2-dichloroethane or 1,2-dibromoethane. Chloro/bromomethyl ketones are prepared in moderate efficiencies in one step using Ph3PAuNTf2 as the catalyst and 8-methylquinoline N-oxide as the oxidant." @default.
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- W2144127521 date "2012-01-01" @default.
- W2144127521 modified "2023-10-05" @default.
- W2144127521 title "Electrophilicity of α-oxo gold carbene intermediates: halogen abstractions from halogenated solvents leading to the formation of chloro/bromomethyl ketones" @default.
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- W2144127521 doi "https://doi.org/10.1039/c2ob25235j" @default.
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