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- W2144209622 startingPage "10439" @default.
- W2144209622 abstract "A novel trigeminal zinc porphyrin sensitizer (T) and two zinc porphyrin monomers (M1 and M2) were successfully designed and synthesized. The spectral, electrochemical, and photovoltaic properties of the porphyrin dyes were investigated. Compared with M1, the molecule of M2 has an additional aliphatic n-hexyloxyl chain at the meso-position of the porphyrin framework, and such a structure is favorable for the formation of a compact hydrophobic layer at the TiO2 surface and the retardation of the diffusion of I3− ions into the nanoporous TiO2 electrode, resulting in more effective suppression of the charge recombination process and a higher Voc. Meanwhile, M2 has larger IPCE values than those of M1, leading to the higher Jsc value. Thus, the DSSC devices based on M2 demonstrated a relatively high power conversion efficiency of 5.77%, with the Jsc, Voc and ff values of 13.93 mA cm−2, 732 mV, and 0.566, respectively. Even though dye T has the highest molar absorption coefficients and multiple binding moieties, the corresponding power conversion efficiency is 2.30%, which is lower than those for M1 and M2. These observations may be ascribed to the low efficiency of the electron injection process caused by the isolation of the LUMOs from the anchoring carboxyl groups in addition to the lowest adsorption amount." @default.
- W2144209622 created "2016-06-24" @default.
- W2144209622 creator A5039051455 @default.
- W2144209622 creator A5060858375 @default.
- W2144209622 creator A5066117003 @default.
- W2144209622 creator A5066654082 @default.
- W2144209622 creator A5089417027 @default.
- W2144209622 date "2014-01-01" @default.
- W2144209622 modified "2023-10-01" @default.
- W2144209622 title "A novel trigeminal zinc porphyrin and corresponding porphyrin monomers for dye-sensitized solar cells" @default.
- W2144209622 cites W1896289247 @default.
- W2144209622 cites W1966267246 @default.
- W2144209622 cites W1967665986 @default.
- W2144209622 cites W1970483988 @default.
- W2144209622 cites W1974952124 @default.
- W2144209622 cites W1979198302 @default.
- W2144209622 cites W1980216394 @default.
- W2144209622 cites W1981368803 @default.
- W2144209622 cites W1981694397 @default.
- W2144209622 cites W1983592349 @default.
- W2144209622 cites W1984855448 @default.
- W2144209622 cites W1989462385 @default.
- W2144209622 cites W1992917598 @default.
- W2144209622 cites W1996829882 @default.
- W2144209622 cites W1997590716 @default.
- W2144209622 cites W1998613997 @default.
- W2144209622 cites W1998851277 @default.
- W2144209622 cites W2001818906 @default.
- W2144209622 cites W2002262949 @default.
- W2144209622 cites W2002424222 @default.
- W2144209622 cites W2003373011 @default.
- W2144209622 cites W2004698822 @default.
- W2144209622 cites W2005683301 @default.
- W2144209622 cites W2005967164 @default.
- W2144209622 cites W2016800344 @default.
- W2144209622 cites W2017220615 @default.
- W2144209622 cites W2017588499 @default.
- W2144209622 cites W2017914440 @default.
- W2144209622 cites W2021890161 @default.
- W2144209622 cites W2022592754 @default.
- W2144209622 cites W2025314342 @default.
- W2144209622 cites W2030372083 @default.
- W2144209622 cites W2033348850 @default.
- W2144209622 cites W2033708153 @default.
- W2144209622 cites W2034314318 @default.
- W2144209622 cites W2043831333 @default.
- W2144209622 cites W2044591029 @default.
- W2144209622 cites W2044939149 @default.
- W2144209622 cites W2045605574 @default.
- W2144209622 cites W2048692523 @default.
- W2144209622 cites W2049225810 @default.
- W2144209622 cites W2049243397 @default.
- W2144209622 cites W2054737018 @default.
- W2144209622 cites W2055428380 @default.
- W2144209622 cites W2057594988 @default.
- W2144209622 cites W2058950487 @default.
- W2144209622 cites W2058950832 @default.
- W2144209622 cites W2059547193 @default.
- W2144209622 cites W2060429075 @default.
- W2144209622 cites W2062852634 @default.
- W2144209622 cites W2063711078 @default.
- W2144209622 cites W2064195144 @default.
- W2144209622 cites W2064937078 @default.
- W2144209622 cites W2065958683 @default.
- W2144209622 cites W2070472558 @default.
- W2144209622 cites W2071409642 @default.
- W2144209622 cites W2071838602 @default.
- W2144209622 cites W2072246233 @default.
- W2144209622 cites W2074063952 @default.
- W2144209622 cites W2076824100 @default.
- W2144209622 cites W2078146328 @default.
- W2144209622 cites W2079357390 @default.
- W2144209622 cites W2080615437 @default.
- W2144209622 cites W2086832880 @default.
- W2144209622 cites W2091251125 @default.
- W2144209622 cites W2097894171 @default.
- W2144209622 cites W2099478233 @default.
- W2144209622 cites W2106437986 @default.
- W2144209622 cites W2108044367 @default.
- W2144209622 cites W2109570507 @default.
- W2144209622 cites W2116327492 @default.
- W2144209622 cites W2121304740 @default.
- W2144209622 cites W2125835134 @default.
- W2144209622 cites W2134823940 @default.
- W2144209622 cites W2136545558 @default.
- W2144209622 cites W2143726431 @default.
- W2144209622 cites W2145408306 @default.
- W2144209622 cites W2147062409 @default.
- W2144209622 cites W2148284063 @default.
- W2144209622 cites W2156086673 @default.
- W2144209622 cites W2156364109 @default.
- W2144209622 cites W2160697401 @default.
- W2144209622 cites W2168199667 @default.
- W2144209622 cites W2171920447 @default.
- W2144209622 cites W2316625228 @default.
- W2144209622 cites W2321918240 @default.
- W2144209622 cites W2325789291 @default.
- W2144209622 cites W2326689755 @default.