Matches in SemOpenAlex for { <https://semopenalex.org/work/W2144272227> ?p ?o ?g. }
- W2144272227 endingPage "381" @default.
- W2144272227 startingPage "372" @default.
- W2144272227 abstract "A group of novel polyacetylenes containing BODIPY pendants have been synthesized in satisfactory yield using a [Rh(nbd)Cl]2–Et3N catalyst. The pendant BODIPY unit has been directly conjugated to the polyacetylene backbone either through the 8 position of the BODIPY cores in P1, or through the 3 position in P2 and P3. Their optoelectronic properties have been investigated by UV-vis, FL, CV and Z-scan techniques. Interestingly, the spectroscopy results show that little electronic interaction exists between the BODIPY chromophoric units and the polyacetylene main chain for P1. However, the electronic interaction between the side pendant and the main chain becomes notable for P2 and P3, resulting in a significant broadening and red-shift of their UV-vis absorption and fluorescence emission wavelengths in comparison with those of their respective monomers. The polymers display thermal stabilities and nonlinear optical properties that are dependent on the connectivities of the BODIPY pendants and the polyacetylene backbones. P1 exhibits relatively better thermal stability and poorer nonlinear optical properties than P1 and P2. The third-order nonlinear optical coefficient (χ(3)) of P1 is 8.5 × 10−12 esu, which is shown to be ∼15 times smaller than those of P2 and P3." @default.
- W2144272227 created "2016-06-24" @default.
- W2144272227 creator A5020776958 @default.
- W2144272227 creator A5025418815 @default.
- W2144272227 creator A5040098877 @default.
- W2144272227 creator A5048826252 @default.
- W2144272227 creator A5061100767 @default.
- W2144272227 creator A5061635039 @default.
- W2144272227 creator A5085698762 @default.
- W2144272227 creator A5086981624 @default.
- W2144272227 date "2014-01-01" @default.
- W2144272227 modified "2023-09-24" @default.
- W2144272227 title "Polyacetylenes containing BODIPY pendants with different connectivities: synthesis, characterization and opto-electronic properties" @default.
- W2144272227 cites W1974969192 @default.
- W2144272227 cites W1976442194 @default.
- W2144272227 cites W1977291855 @default.
- W2144272227 cites W1977605072 @default.
- W2144272227 cites W1977830487 @default.
- W2144272227 cites W1982509045 @default.
- W2144272227 cites W1983435054 @default.
- W2144272227 cites W1983724761 @default.
- W2144272227 cites W1983797776 @default.
- W2144272227 cites W1984022825 @default.
- W2144272227 cites W1986306298 @default.
- W2144272227 cites W1989595818 @default.
- W2144272227 cites W1994018743 @default.
- W2144272227 cites W1996541351 @default.
- W2144272227 cites W1997761064 @default.
- W2144272227 cites W1997855068 @default.
- W2144272227 cites W1998239211 @default.
- W2144272227 cites W2000128160 @default.
- W2144272227 cites W2004347549 @default.
- W2144272227 cites W2006966910 @default.
- W2144272227 cites W2007942409 @default.
- W2144272227 cites W2009057700 @default.
- W2144272227 cites W2016630522 @default.
- W2144272227 cites W2021149057 @default.
- W2144272227 cites W2028170873 @default.
- W2144272227 cites W2028822778 @default.
- W2144272227 cites W2030260629 @default.
- W2144272227 cites W2033093826 @default.
- W2144272227 cites W2038126151 @default.
- W2144272227 cites W2039639359 @default.
- W2144272227 cites W2040079395 @default.
- W2144272227 cites W2048330733 @default.
- W2144272227 cites W2048369320 @default.
- W2144272227 cites W2049444651 @default.
- W2144272227 cites W2050897858 @default.
- W2144272227 cites W2051498016 @default.
- W2144272227 cites W2055499045 @default.
- W2144272227 cites W2057114420 @default.
- W2144272227 cites W2057194572 @default.
- W2144272227 cites W2073019018 @default.
- W2144272227 cites W2078030115 @default.
- W2144272227 cites W2083062963 @default.
- W2144272227 cites W2095472229 @default.
- W2144272227 cites W2097578667 @default.
- W2144272227 cites W2102199698 @default.
- W2144272227 cites W2110449015 @default.
- W2144272227 cites W2116646800 @default.
- W2144272227 cites W2118144971 @default.
- W2144272227 cites W2121083268 @default.
- W2144272227 cites W2123640313 @default.
- W2144272227 cites W2125964625 @default.
- W2144272227 cites W2136895416 @default.
- W2144272227 cites W2143560071 @default.
- W2144272227 cites W2145719680 @default.
- W2144272227 cites W2159651508 @default.
- W2144272227 cites W2171716783 @default.
- W2144272227 cites W2317671948 @default.
- W2144272227 cites W2318793533 @default.
- W2144272227 cites W2324420853 @default.
- W2144272227 cites W4236161930 @default.
- W2144272227 cites W4376848345 @default.
- W2144272227 doi "https://doi.org/10.1039/c3py01021j" @default.
- W2144272227 hasPublicationYear "2014" @default.
- W2144272227 type Work @default.
- W2144272227 sameAs 2144272227 @default.
- W2144272227 citedByCount "20" @default.
- W2144272227 countsByYear W21442722272015 @default.
- W2144272227 countsByYear W21442722272016 @default.
- W2144272227 countsByYear W21442722272017 @default.
- W2144272227 countsByYear W21442722272019 @default.
- W2144272227 countsByYear W21442722272020 @default.
- W2144272227 crossrefType "journal-article" @default.
- W2144272227 hasAuthorship W2144272227A5020776958 @default.
- W2144272227 hasAuthorship W2144272227A5025418815 @default.
- W2144272227 hasAuthorship W2144272227A5040098877 @default.
- W2144272227 hasAuthorship W2144272227A5048826252 @default.
- W2144272227 hasAuthorship W2144272227A5061100767 @default.
- W2144272227 hasAuthorship W2144272227A5061635039 @default.
- W2144272227 hasAuthorship W2144272227A5085698762 @default.
- W2144272227 hasAuthorship W2144272227A5086981624 @default.
- W2144272227 hasConcept C112613896 @default.
- W2144272227 hasConcept C120665830 @default.
- W2144272227 hasConcept C121332964 @default.
- W2144272227 hasConcept C166940927 @default.
- W2144272227 hasConcept C178790620 @default.