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• W2144328440 endingPage "331" @default.
• W2144328440 startingPage "323" @default.
• W2144328440 abstract "The vibrational structure of the first bands of the photoelectron (PE) spectra of the radicals SiH 3 , CF 3 , CH 2 CN and CH 2 NC has been calculated by means of the Coupled Electron Pair Approximation. Excellent agreement with experiment is obtained for SiH 3 . A long progression in the umbrella bending vibration is calculated for CF 3 . Furthermore, two combination tone series should be observable in the PE spectrum at higher resolution. The PE spectra of CH 2 CN and CH 2 NC are dominated by the adiabatic peaks. Adiabatic ionization potentials of 8.98 ±0.05 eV, 10.20±0.05 eV and 9.36±0.03 eV are predicted for CF 3 , CH 2 CN and CH 2 NC" @default.
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• W2144328440 date "1995-03-01" @default.
• W2144328440 modified "2023-09-25" @default.
• W2144328440 title "Calculated Vibrational Structure of the Photoelectron Spectra of Free Radicals" @default.
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• W2144328440 doi "https://doi.org/10.1002/bbpc.19950990312" @default.
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