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• W2144332013 abstract "Abstract The study of the hydrogen/deuterium exchange reactions of the C(2)‐proton for different carbene precursors has been carried out in the absence and presence of β‐cyclodextrin in D 2 O at 25°C. Formation of the inclusion complexes of imidazolium salts with the native β‐cyclodextrin and the β‐dimethylcyclodextrin is demonstrated by 1D and 2D 1 H NMR, ESI/HRMS and a molecular modelling study. Formation of the inclusion complexes of imidazolium salts with the native β‐cyclodextrin and the β‐dimethylcyclodextrin is a simple and efficient method to modify the acidity of the imidazolium H(2) and to modify its environment. Encapsulation of 1,3‐disubstituted imidazolium chloride by β‐cyclodextrins results in the inhibition of the H(2)/D exchange in the complex. Copyright © 2008 John Wiley & Sons, Ltd." @default.
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• W2144332013 date "2008-07-21" @default.
• W2144332013 modified "2023-10-14" @default.
• W2144332013 title "Supramolecular encapsulation of 1,3-bis(1-adamantyl)imidazolium chloride by β-cyclodextrins: towards inhibition of C(2)-H/D exchange" @default.
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• W2144332013 doi "https://doi.org/10.1002/poc.1423" @default.
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