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• W2144340315 endingPage "832" @default.
• W2144340315 startingPage "828" @default.
• W2144340315 abstract "Benzene and methanol make a minimum boiling point homogeneous binary azeotrope with the mole ratio 2:3. Some characteristic vibrational modes, as well as (1)H NMR signals change due to the azeotrope formation. The extend of interaction of these molecules causes significant changes on some vibrational modes involved, and (1)H NMR signals show some changes on their position. No IR, Raman, and NMR spectra have been reported for this constant boiling mixture, also there has not been any attempt to investigate the unit-structure of this azeotrope. In this work the FTIR, FT-Raman, and (1)H NMR spectra of pure benzene, pure methanol, and corresponding azeotrope were recorded, mutual influences resulting from azeotrope formation have been analyzed, and spectral changes has been discussed. The unit-structure of cluster has been deduced based on mole ratio, boiling point depression of constituents, and comparison among the spectra obtained by FTIR, FT-Raman, and (1)H NMR techniques." @default.
• W2144340315 created "2016-06-24" @default.
• W2144340315 creator A5023055479 @default.
• W2144340315 creator A5063313167 @default.
• W2144340315 date "2009-09-01" @default.
• W2144340315 modified "2023-10-16" @default.
• W2144340315 title "Spectra and structure of binary azeotropes VI-benzene-methanol" @default.
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• W2144340315 doi "https://doi.org/10.1016/j.saa.2009.04.020" @default.
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