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• W2144360257 abstract "Abstract Succinonitrile is the precursor of 1,4‐diaminobutane, which is used for the industrial production of polyamides. This paper describes the synthesis of biobased succinonitrile from glutamic acid and glutamine, amino acids that are abundantly present in many plant proteins. Synthesis of the intermediate 3‐cyanopropanoic amide was achieved from glutamic acid 5‐methyl ester in an 86 mol % yield and from glutamine in a 56 mol % yield. 3‐Cyanopropanoic acid can be converted into succinonitrile, with a selectivity close to 100 % and a 62 % conversion, by making use of a palladium(II)‐catalyzed equilibrium reaction with acetonitrile. Thus, a new route to produce biobased 1,4‐diaminobutane has been discovered." @default.
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• W2144360257 date "2011-05-10" @default.
• W2144360257 modified "2023-10-18" @default.
• W2144360257 title "Synthesis of Biobased Succinonitrile from Glutamic Acid and Glutamine" @default.
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• W2144360257 doi "https://doi.org/10.1002/cssc.201100030" @default.
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