Matches in SemOpenAlex for { <https://semopenalex.org/work/W2144367036> ?p ?o ?g. }
- W2144367036 endingPage "2598" @default.
- W2144367036 startingPage "2583" @default.
- W2144367036 abstract "A series of palladium nanoparticles stabilized by five chiral sugar-based oxazolinyl-phosphite ligands, containing various substituents at the oxazoline and phosphite moieties has been synthesized. They were characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), infrared spectroscopy (IR) and elemental analysis. These nanoparticles were applied in Pd-catalyzed asymmetric allylic alkylation and Heck coupling reactions. A detailed study to elucidate the nature of the active species using a continuous-flow membrane reactor (CFMR), accompanied by TEM observations, classical poisoning experiments, and kinetic measurements have been carried out. Conclusive evidence of the nature of the species involved in the use of PdNPs in asymmetric catalytic reactions has been obtained. The CFMR experiments proved the molecular nature of the true catalysts and all conversions can be justified by the amount of molecular palladium that leached as measured by ICP-AES." @default.
- W2144367036 created "2016-06-24" @default.
- W2144367036 creator A5028972539 @default.
- W2144367036 creator A5029350135 @default.
- W2144367036 creator A5055299896 @default.
- W2144367036 creator A5055752156 @default.
- W2144367036 creator A5070975248 @default.
- W2144367036 creator A5073088693 @default.
- W2144367036 creator A5084527048 @default.
- W2144367036 date "2008-11-03" @default.
- W2144367036 modified "2023-10-09" @default.
- W2144367036 title "Palladium Nanoparticles in Allylic Alkylations and Heck Reactions: The Molecular Nature of the Catalyst Studied in a Membrane Reactor" @default.
- W2144367036 cites W1540559052 @default.
- W2144367036 cites W1965744979 @default.
- W2144367036 cites W1969462380 @default.
- W2144367036 cites W1970800627 @default.
- W2144367036 cites W1975270017 @default.
- W2144367036 cites W1976085475 @default.
- W2144367036 cites W1979884986 @default.
- W2144367036 cites W1982284738 @default.
- W2144367036 cites W1986001811 @default.
- W2144367036 cites W1986489572 @default.
- W2144367036 cites W1988373554 @default.
- W2144367036 cites W1990753128 @default.
- W2144367036 cites W1994359355 @default.
- W2144367036 cites W1998915746 @default.
- W2144367036 cites W2003037497 @default.
- W2144367036 cites W2009066560 @default.
- W2144367036 cites W2011996195 @default.
- W2144367036 cites W2012007763 @default.
- W2144367036 cites W2013245372 @default.
- W2144367036 cites W2014750689 @default.
- W2144367036 cites W2016260972 @default.
- W2144367036 cites W2018013371 @default.
- W2144367036 cites W2022704527 @default.
- W2144367036 cites W2025443759 @default.
- W2144367036 cites W2025449370 @default.
- W2144367036 cites W2026766028 @default.
- W2144367036 cites W2028572110 @default.
- W2144367036 cites W2041250150 @default.
- W2144367036 cites W2044571535 @default.
- W2144367036 cites W2044666539 @default.
- W2144367036 cites W2049095005 @default.
- W2144367036 cites W2053836759 @default.
- W2144367036 cites W2060443393 @default.
- W2144367036 cites W2064257793 @default.
- W2144367036 cites W2066651830 @default.
- W2144367036 cites W2066838427 @default.
- W2144367036 cites W2067321229 @default.
- W2144367036 cites W2070381091 @default.
- W2144367036 cites W2073849165 @default.
- W2144367036 cites W2074174452 @default.
- W2144367036 cites W2074709074 @default.
- W2144367036 cites W2075031710 @default.
- W2144367036 cites W2075264181 @default.
- W2144367036 cites W2076882723 @default.
- W2144367036 cites W2079574222 @default.
- W2144367036 cites W2079760524 @default.
- W2144367036 cites W2079902319 @default.
- W2144367036 cites W2080328478 @default.
- W2144367036 cites W2081189631 @default.
- W2144367036 cites W2081956351 @default.
- W2144367036 cites W2082139032 @default.
- W2144367036 cites W2084624770 @default.
- W2144367036 cites W2090404699 @default.
- W2144367036 cites W2091117905 @default.
- W2144367036 cites W2092572447 @default.
- W2144367036 cites W2095699544 @default.
- W2144367036 cites W2096595566 @default.
- W2144367036 cites W2097981175 @default.
- W2144367036 cites W2099615748 @default.
- W2144367036 cites W2102515376 @default.
- W2144367036 cites W2104062416 @default.
- W2144367036 cites W2104947409 @default.
- W2144367036 cites W2105846569 @default.
- W2144367036 cites W2107716124 @default.
- W2144367036 cites W2114424373 @default.
- W2144367036 cites W2118784766 @default.
- W2144367036 cites W2120437993 @default.
- W2144367036 cites W2120634307 @default.
- W2144367036 cites W2132426585 @default.
- W2144367036 cites W2134288587 @default.
- W2144367036 cites W2138674119 @default.
- W2144367036 cites W2141453896 @default.
- W2144367036 cites W2150817845 @default.
- W2144367036 cites W2151888533 @default.
- W2144367036 cites W2154243348 @default.
- W2144367036 cites W2156712416 @default.
- W2144367036 cites W2157376567 @default.
- W2144367036 cites W2167969142 @default.
- W2144367036 cites W2316757814 @default.
- W2144367036 cites W2490616660 @default.
- W2144367036 cites W2744571369 @default.
- W2144367036 cites W2950546757 @default.
- W2144367036 cites W2951178848 @default.
- W2144367036 cites W2952098552 @default.
- W2144367036 cites W2952765784 @default.
- W2144367036 cites W2952951542 @default.