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• W2144583647 abstract "We found direct experimental evidence for an orbital switching in the V 3d states across the metal-insulator transition in VO$_{2}$. We have used soft-x-ray absorption spectroscopy at the V $L_{2,3}$ edges as a sensitive local probe, and have determined quantitatively the orbital polarizations. These results strongly suggest that, in going from the metallic to the insulating state, the orbital occupation changes in a manner that charge fluctuations and effective band widths are reduced, that the system becomes more 1-dimensional and more susceptible to a Peierls-like transition, and that the required massive orbital switching can only be made if the system is close to a Mott insulating regime." @default.
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• W2144583647 date "2005-11-02" @default.
• W2144583647 modified "2023-10-18" @default.
• W2144583647 title "Orbital-Assisted Metal-Insulator Transition in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mi>VO</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math>" @default.
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• W2144583647 doi "https://doi.org/10.1103/physrevlett.95.196404" @default.
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