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- W2144610212 abstract "A one-pot reaction of 3-trimethylsilylprop-2-enyl(diisobutyl)telluronium bromide 1 with α,β-unsaturated ketones gives, by way of Michael addition in the presence of caesium carbonate under solid–liquid phase-transfer conditions, trimethylsilylvinylcyclopropanes both in high to excellent yields and with high stereoselectivity. A similar high-yielding cyclopropanation occurs in THF/trace of water with diisobutyl telluride as catalyst in a one-pot reaction of (E)-3-bromo-1-trimethylsilylprop-1-ene with α,β-unsaturated ketones in the presence of caesium carbonate." @default.
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- W2144610212 date "1994-01-01" @default.
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- W2144610212 title "An efficient and highly stereoselective synthesis of trimethylsilylvinylcyclopropane derivatives via an organotelluronium salt: first example of catalytic Wittig-type cyclopropanation" @default.
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- W2144610212 doi "https://doi.org/10.1039/p19940000893" @default.
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