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- W2144635950 abstract "Abstract By irradiation in oxygen-free ether α- or β-substituted β-morpholinopropiophenones 1a-c form the corresponding cyclopropanols 2 with 1-aryl and 2-morpholino group in a relative cis-configuration in high yields. The photocyclization of pure 1a-c enantiomers proceeds enantioselectively under these conditions. In methanol and presence of oxygen electronically excited 1c-h are converted to enaminones 3c-h via oxidation of intermediate cyclopropanols 2c-h. In the presence of electron-acceptor molecules this reaction apparently follows a SET mechanism." @default.
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- W2144635950 date "1993-10-01" @default.
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- W2144635950 title "The influence of substituents on the photochemical generation and stability of 2-morpholinocyclopropanols" @default.
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- W2144635950 doi "https://doi.org/10.1016/s0040-4039(00)61688-x" @default.
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