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- W2144654345 abstract "Trans-disubstituted β-lactams show increasing utility and prominence in numerous pharmaceutical applications, making their asymmetric synthesis an attractive goal for chemists. We introduce an anionic, nucleophilic catalyst system that provides an efficient, diastereoselective route to trans-disubstituted β-lactams, a complement to our previously described catalytic methodology for generating the corresponding cis diastereomers. This catalytic, “switch mechanism” process allows for flexibility in the stereoselective synthesis of β-lactams, producing either cis or trans products as desired from the same substrates." @default.
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- W2144654345 date "2005-07-06" @default.
- W2144654345 modified "2023-10-16" @default.
- W2144654345 title "An Anionic Nucleophilic Catalyst System for the Diastereoselective Synthesis of <i>trans</i>-β-Lactams" @default.
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- W2144654345 doi "https://doi.org/10.1021/ol0511070" @default.
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