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- W2144662803 abstract "Abstract Formation equilibria and aquation kinetics of the monomalonatochromium(III) ion were investigated in acid solutions of ionic strength μ = 2. [Cr( mal ) aq 4 ] + is stable in absence of excess malonate at pH ≳ 2; at lower pH it is progressively aquated, giving eventually complete aquation to [ Craq 6 ] +3 below pH 0.6. The aquation reaction is pseudo‐first order with k = k 0 + k 1 [H + ]. The activation energies are δH = 24.9 and 19.4 kcal/mole for the k 0 and k 1 paths respectively. A comparison with the corresponding oxalato complexes shows that the smaller stability of the malonatocomplexes is of conditional nature, and depends to a great extent on the much larger protonation constants of the ligand anion." @default.
- W2144662803 created "2016-06-24" @default.
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- W2144662803 date "1969-02-01" @default.
- W2144662803 modified "2023-10-16" @default.
- W2144662803 title "A solution Study of the Malonatotetraquochromium(III) Ion" @default.
- W2144662803 cites W2014170503 @default.
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- W2144662803 doi "https://doi.org/10.1002/zaac.19693640513" @default.
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