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- W2144799056 abstract "Three new compounds based on alkaline earth element ions and 4,4′-oxy-bis(benzoic acid) (OBA) were synthesized and characterized. Compound 1, [Ca(H2O)(OBA)], consists of a Ca2O10 dimer, which is connected through OBA anions to form the three-dimensional structure. While in compound 2, [Sr(H2O)(OBA)], SrO7 units are connected to form one-dimensional chains, which are in-turn connected by OBA anions to form the three-dimensional architecture. In compound 3, [Ba2O3(OBA)2], BaO8 and BaO9 units are connected to form the 6-membered two-dimensional sheet structure. These two-dimensional layers are pillared by OBA anions to complete the three-dimensional connectivity. Variable temperature powder X-ray diffraction and thermogravimetric analysis studies show that all these structures are thermally stable up to 400 °C. We have measured the optical band gap energies and results show that the values decrease slightly from 1 to 3. This variation in band gap energy may be due to the different architectures, which affect the states of conduction and valence bands of the materials." @default.
- W2144799056 created "2016-06-24" @default.
- W2144799056 creator A5016072367 @default.
- W2144799056 creator A5061861077 @default.
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- W2144799056 date "2014-08-18" @default.
- W2144799056 modified "2023-09-24" @default.
- W2144799056 title "Synthesis, structure and band gap energy of a series of thermostable alkaline earth metal based metal–organic frameworks" @default.
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- W2144799056 doi "https://doi.org/10.1039/c4ce01505c" @default.
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